Energy of the quasi-free electron in low density Ar and Kr: Extension of the local Wigner-Seitz model

نویسندگان

  • Xianbo Shi
  • Luxi Li
  • Gina Moriarty
  • C. M. Evans
  • G. L. Findley
چکیده

We present new measurements of the perturber induced shift of the CH3I ionization energy at low perturber number densities and analyze these data within the local Wigner-Seitz model previously used at high density. We compare the local Wigner-Seitz model with the scattering approach developed by Fermi, and modified by Alekseev and Sobel’man, and show that the local Wigner-Seitz model extends smoothly into the low density region and accurately predicts the temperature dependence of the shift in ionization energy.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Energy of the quasi-free electron in supercritical argon near the critical point

Field ionization of high-n CH3I Rydberg states doped into argon is presented as a function of argon number density along the critical isotherm. These data exhibit a decrease in the argon induced shift of the dopant ionization energy near the critical point. We show that this decrease is due to the interaction between argon and the quasi-free electron arising from field ionization of the dopant....

متن کامل

Energy of the quasi-free electron in xenon

Field ionization of trimethylamine and of N,N-dimethylaniline doped into xenon is presented as a function of xenon number density up to the density of the triple point liquid, both at noncritical temperatures and along the critical isotherm. These data exhibit a decrease in the xenon induced shift of the dopant ionization energy near the xenon critical point. The energy of the quasi-free electr...

متن کامل

Energy of the quasi-free electron in argon, krypton and xenon

Recent field ionization measurements of various high-n molecular Rydberg states doped into argon, krypton and xenon perturbers are presented as a function of perturber number density up to the density of the triple point liquid. These data are modeled to within ±0.3% of experiment on both critical and noncritical isotherms using a new theoretical treatment that includes: (i) the polarization of...

متن کامل

Field Ionization of C2H5I in Supercritical Argon near the Critical Point

Field ionization of C2H5I doped into argon is presented as a function of argon number density along the argon critical isotherm. These data exhibit a decrease in the argon induced shift of the C2H5I ionization energy near the critical point similar to recent field ionization measurements of CH3I/Ar. We show that this decrease is due to the interaction between argon and the quasi-free electron a...

متن کامل

THE EXTENDED LAW OF CORRESPONDING - STATES AND THE INTERMOLECULAR POTENTIALS FOR Ar-Ar, Ar-Kr AND Kr-Kr

An inversion procedure is used to obtain from the extended principle of corresponding - states the pair interaction potentials for argon, krypton and its mixture over a tetnperature range from absolute zero to the onset of ionization. The experimentally-reduced viscosity collision integrals obtained from the corresponding - states correlation have been inverted directly to give the reduced...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2007